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Ants primarily attack snakes for one of two reasons:

When a queensnake accidentally disturbs an underground ant nest or gets trapped on land during a molt or injury, the ants release alarm pheromones. Within seconds, hundreds of ants swarm the reptile. Ants like fire ants use a two-pronged attack: they bite with their mandibles to anchor themselves, then inject a toxic venom containing solenopsin using their stingers. To a cold-blooded snake, this causes an intense, burning sensation across its entire body. 2. Exploiting Vulnerabilities